Converting Between Celsius and Kelvin
Adding and subtracting 273.15
Lesson 89 of 4,500 · Measurement, Units and SI
Learning objectives
- Convert temperatures from Celsius to kelvin and back
- Explain why temperature differences are identical in °C and K
- Decide when to use 273.15 and when 273 is acceptable
Introduction
Laboratory thermometers are marked in degrees Celsius, but the equations of chemistry need kelvin. Every time you use a gas law or a thermodynamic equation, you must switch between the two scales. Fortunately, the conversion is one of the simplest in science: because the two scales have steps of the same size, you only add or subtract a fixed number. Getting it right quickly and confidently will save you marks throughout your chemistry course.
Core explanation
Same step size, different zero. Celsius and kelvin scales are like two rulers with identical markings, one slid along the other. A rise of 1 °C equals a rise of 1 K. The only difference is where zero sits. Zero on the kelvin scale is absolute zero; zero on the Celsius scale is 273.15 K. The gap between the zeros — the offset — is exactly 273.15.
The conversion equations.
T(K) = θ(°C) + 273.15
θ(°C) = T(K) − 273.15
(Scientists often use θ, theta, for Celsius temperature and T for kelvin temperature.) To go from Celsius to kelvin, add 273.15. To go from kelvin to Celsius, subtract 273.15.
273 or 273.15? The exact offset is 273.15. However, most laboratory thermometers read only to the nearest 0.5 °C or 1 °C, so the extra 0.15 makes no meaningful difference. Many exam boards accept 273 for everyday conversions. Use 273.15 when temperatures are given to two decimal places, or when a question asks for it. Keep your answer's precision consistent with the data: 25 °C becomes 298 K, while 25.00 °C becomes 298.15 K.
Temperature differences need no conversion. Because the steps are the same size, a change of 15 °C is a change of 15 K. If water warms from 18 °C to 33 °C, ΔT = 15 K. Adding 273 to both temperatures and then subtracting gives the same answer, because the offsets cancel. This is useful in energy calculations such as heating a known mass of water.
Common reference temperatures.
Description °C K --- --- --- Absolute zero −273.15 0 Freezing point of water 0 273.15 Standard thermodynamic temperature 25 298.15 Normal human body 37 310.15 Boiling point of water (1 atm) 100 373.15
Sanity checks. A kelvin temperature is always 273 larger than the Celsius value, and it can never be negative. If you convert a temperature and get a negative kelvin value, you have subtracted instead of added.
Formulae
T(K) = θ(°C) + 273.15 and θ(°C) = T(K) − 273.15. A temperature difference ΔT has the same value in K and °C.
Step-by-step reasoning
To convert −40 °C into kelvin:
1. Identify the direction: Celsius to kelvin, so add. 2. Calculate −40 + 273.15 = 233.15. 3. Round to match the data: −40 °C has no decimal places, so write 233 K. 4. Check: the answer is positive and 273 more than the Celsius value.
Visual explanation
Draw two vertical number lines side by side, with equal spacing. Label the left one in °C with 0 at water's freezing point, and the right one in K with 273 beside it. A horizontal arrow from any Celsius value to the kelvin line shows the same point on both scales, always 273.15 units higher on the kelvin side.
Real-world analogy
Converting between Celsius and kelvin is like converting a building's floor numbers between two systems where one counts from the basement car park three floors down. Every floor number is simply three higher in the second system, and climbing two floors is still climbing two floors in either system.
Real-world example
Weather forecasts use Celsius, but scientists studying the atmosphere often use kelvin. The average surface temperature of the Earth is about 15 °C, or 288 K. Climate models calculate the energy radiated by the Earth using kelvin temperatures, because the equations only work from absolute zero.
Why?
Why do temperature differences not need converting? Both temperatures are shifted by the same 273.15. When you subtract one from the other, the shift cancels out. Only the step size matters for a difference, and the step size is identical on both scales.
Common misconception
"To convert a temperature change from °C to K, add 273." This is wrong. A change of 10 °C is a change of 10 K, not 283 K. Only actual temperatures need the offset; differences do not.
Worked example
Question: Liquid nitrogen boils at 77 K. Oxygen boils at −183 °C. Express both in the same units and state which boils at the higher temperature.
Reasoning: Convert nitrogen to Celsius: 77 − 273 = −196 °C. Convert oxygen to kelvin: −183 + 273 = 90 K. Compare: 90 K is higher than 77 K.
Answer: Nitrogen: −196 °C (77 K); oxygen: −183 °C (90 K). Oxygen boils at the higher temperature.
Quick check
1. Convert 350 K into degrees Celsius. Answer: 350 − 273 = 77 °C (76.85 °C using 273.15).
Exam focus
Examiners test conversions in gas law and energy questions. Always convert actual temperatures to kelvin before substituting into gas equations, but use the change directly for ΔT. Show the addition clearly, and match decimal places to the data given.
Advanced insight
Other temperature scales exist. The Fahrenheit scale, still used in the USA, has different step sizes (1 °C = 1.8 °F), so converting needs both a multiplication and an offset. The Rankine scale is an absolute scale with Fahrenheit-sized steps. The kelvin–Celsius pair is unusual in needing only an offset, because the Celsius scale is now officially defined from the kelvin.
Summary
Celsius and kelvin have the same step size but different zeros, separated by 273.15. Add 273.15 to convert °C to K; subtract it to convert K to °C. Using 273 is acceptable for most laboratory data. Temperature differences have the same value in both scales, and a kelvin temperature can never be negative.
Practice questions
1. Convert 25 °C into kelvin. Answer: 25 + 273 = 298 K. 2. Convert 200 K into degrees Celsius. Answer: 200 − 273 = −73 °C. 3. The temperature of a solution rises from 21.0 °C to 29.5 °C. What is the rise in kelvin? Answer: 8.5 K, because a difference is the same on both scales. 4. A student converts 50 °C and gets −223 K. What mistake was made, and what is the correct value? Answer: They subtracted 273 instead of adding it; the correct value is 323 K.